Skeptophilia (skep-to-fil-i-a) (n.) - the love of logical thought, skepticism, and thinking critically. Being an exploration of the applications of skeptical thinking to the world at large, with periodic excursions into linguistics, music, politics, cryptozoology, and why people keep seeing the face of Jesus on grilled cheese sandwiches.
Showing posts with label binding energy curve. Show all posts
Showing posts with label binding energy curve. Show all posts

Wednesday, December 14, 2022

Ahead of the curve

I remember how stunned I was when I was in high school and found out that all energy release -- from striking a match to setting off a nuclear bomb -- goes back to Einstein's famous equation, that energy is equal to mass times the speed of light squared.

It all hinges on the fact that the Law of Conservation of Mass isn't quite right.  If I set a piece of paper on fire inside a sealed box, the oft-quoted line in middle school textbooks -- that if I'd weighed the paper and the air in the box beforehand and then reweighed the ash and the air in the box afterward, they'd have identical masses -- isn't true.  The fact is, the box would weigh less after the paper had burned completely.

The reason is that some (a very tiny amount, but some) of the mass of the paper would have been converted to energy according to Einstein's equivalency, and that's where the heat and light of the fire came from.  Thus, the box and its contents would have less mass than they started with.

The mind-boggling truth is that when you burn a fossil fuel -- oil, coal, or natural gas -- you are re-releasing energy from the Sun that was stored in the tissues of plants in the form of a little bit of extra mass during the Carboniferous Period, three-hundred-odd million years ago.

So to fix the problem with the "Law," we have to account for the shifting back and forth between matter and energy.  If you change it to a conservation law of the total -- that the sum of the mass and energy stays constant in a closed system -- it's spot-on.  (In fact, this is the First Law of Thermodynamics.)

How much energy you can get out of anything depends, then, only on one thing; how much of its mass you can turn into energy.  This is the basis of (amongst many other things) what happens in a nuclear power plant.  As folks like Henri Becquerel, Marie SkÅ‚odowska Curie, Pierre Curie, and others showed in the early twentieth century, the atoms of an element can be turned into the atoms of a different element -- the dream of the alchemists -- and the amount of energy required or released by that process is described by something called the binding energy curve.


This graph shows a number of interesting things.  First, the higher on the graph an atom is, the more stable it is.  Second, when you're going from one atom type to another, if you've moved upward on the graph, that transition releases energy; if you've moved downward, the transition requires energy.  Third, how big a jump you've made is a measure of the amount of energy you release or consume in the transition.  (Theoretically; as you'll see, doing this in the real world, and making practical use of the process, is another matter entirely.)

Note, for example, going from uranium (at the far right end of the graph) to any of the other mid-weight elements uranium breaks down into when it undergoes nuclear fission.  What those are, specifically, isn't that important; they all lie on the flattish part of the curve between iron (Fe, the most stable element) and uranium.  Going from uranium to any of those is an upward movement on the graph, and thus releases energy.  Seems like it must not be much, right?  Well, that "small" release is what generates the energy from a nuclear power plant -- and from bombs of the type that destroyed Hiroshima.

Now check out the other end of the graph -- the elements for which fusion is the energy-releasing transformation.

Go, for example from hydrogen-1 (the very bottom left corner of the graph) to helium-4 (at the peak, right around 7 MeV), and compare the size of that leap with the one from uranium to any of its fission products.  This transition -- hydrogen-1 to helium-4 -- is the one that powers the Sun, and is what scientists would like to get going in a fusion reactor.

See why?  I could sit down and calculate the per-transition difference in the energy release between fission and fusion, but it's huge.  Fusion releases more energy by orders of magnitude.  Also, the fuel for fusion, hydrogen, is by far the most abundant element in the Solar System; it's kind of everywhere.  Not only that, the waste product -- helium -- is completely harmless and inert, by comparison to fission waste, which remains deadly for centuries.

That's why the scientists want so desperately to get fusion going as a viable energy source.

The problem, as I noted earlier, is practicality.  The fusion reactions in the Sun are kept going because the heat and pressure in the core are sufficient for hydrogen nuclei to overcome their mutual electrostatic repulsion, crushing them together and triggering a chain reaction that leads to helium-4 (and releasing a crapload of energy in the process).  Maintaining those conditions in the lab has turned out to be extraordinarily difficult; it's always consumed (far) more energy to trigger nuclear fusion than came out of it, and the reactions are self-limiting, collapsing in a split-second.  It's what's given rise to the sardonic quip, "Practical nuclear fusion is fifty years in the future... and always will be."

Well -- it seems like "fifty years in the future" may have just gotten one step closer.

It was just announced that for the first time ever, scientists at the amusingly-named National Ignition Facility of Livermore, California have created a nuclear fusion reaction that produced more energy than it consumed.  This proof-of-concept is, of course, only the first step, but it demonstrates that practical nuclear fusion might not be the pipe dream it has seemed since its discovery almost a century ago.

"This is a monumental breakthrough," said Gilbert Collins of the University of Rochester in New York, a physicist who has collaborated in other NIF projects but was not involved the current research.  "With this achievement, the landscape has changed...  comparable to the invention of the transistor or the Wright brothers’ first flight.  We now have a laboratory system that we can use as a compass for how to make progress very rapidly."

So keep your eyes on the news.  A common pattern in science is that once someone shows something is possible, the advances take off like a rocket.  Imagine how it would change the world if we could, once and for all, ditch our dependence on fossil fuels and dangerous nuclear fission technology, and power the planet using an energy source that runs on a ridiculously abundant fuel and produces a completely harmless waste product.

That dream may have just gotten one step closer.

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Monday, March 30, 2020

All that glitters

If you own anything made of gold, take a look at it now.

I'm looking at my wedding ring, made of three narrow interlocked gold bands.   It's a little scratched up after almost eighteen years, but still shines.


Have you ever wondered where gold comes from?  Not just "a gold mine," but before that.  If you know a little bit of physics, it's kind of weird that the periodic table doesn't end at 26.  The reason is a subtle but fascinating one, and has to do with the binding energy curve.


The vertical axis is a measure of how tightly the atom's nucleus is held together.  More specifically, it's the amount of energy (in millions of electron-volts) that it would take to completely disassemble the nucleus into its component protons and neutrons.  From hydrogen (atomic number = 1) up to iron (atomic number = 26), there is a relatively steady increase in binding energy.  So in that part of the graph, fusion is an energy-releasing process (moves upward on the graph) and fission is an energy-consuming process (moves downward on the graph).  This, in fact, is what powers the Sun; going from hydrogen to helium is a jump of seven million electron-volts per proton or neutron, and that energy release is what produces the light and heat that keeps us all alive.

After iron, though -- specifically after an isotope of iron, Fe-56, with 26 protons and 30 neutrons -- there's a slow downward slope in the graph.  So after iron, the situation is reversed; fusion would consume energy, and fission would release it.  This is why the fission of uranium-235 generates energy, which is how a nuclear power plant works.

It does generate a question, though.  If fusion in stars is energetically favorable, increasing stability and releasing energy, up to but not past iron -- how do the heavier elements form in the first place?  Going from iron to anywhere would require a consumption of energy, meaning those will not be spontaneous reactions.  They need a (powerful) energy driver.  And yet, some higher-atomic-number elements are quite common -- zinc, iodine, and lead come to mind.

Well, it turns out that there are two ways this can happen, and they both require a humongous energy source.  Like, one that makes the core of the Sun look like a wet firecracker.  Those are supernova explosions, and neutron star collisions.  And just last week, two astrophysicists -- Szabolcs Marka of Columbia University and Imre Bartos of the University of Florida -- found evidence that the heavy elements on the Earth were produced in a collision between two neutron stars, on the order of a hundred million years before the Solar System formed.

This is an event of staggering magnitude.  "If you look up at the sky and you see a neutron-star merger 1,000 light-years away," Marka said, "it would outshine the entire night sky."

What apparently happens is when two neutron stars -- the ridiculously dense remnants of massive stellar cores -- run into each other, it is such a high-energy event that even thermodynamically unfavorable (energy-consuming) reactions can pick up enough energy from the surroundings to occur.  Then some of the debris blasted away from the collision gets incorporated into forming stars and planets -- and here we are, with tons of lightweight elements, but a surprisingly high amount of heavier ones, too.

But how do they know it wasn't a nearby supernova?  Those are far more common in the universe than neutron star collisions.  Well, the theoretical yield of heavy elements is known for each, and the composition of the Solar System is far more consistent with a neutron star collision than with a supernova.  And as for the timing, a chunk of the heavy isotopes produced are naturally unstable, so decaying into lighter nuclei is favored (which is why heavy elements are often radioactive; the products of decay are higher on the binding energy curve than the original element was).  Since this happens at a set rate -- most often calculated as a half-life -- radioactive isotopes act like a nuclear stopwatch, analogous to the way radioisotope decay is used to calculate the ages of artifacts, fossils, and rocks.  Backtracking that stopwatch to t = 0 gives an origin of about 4.7 billion years ago, or a hundred million years before the Solar System coalesced.

So next time you look at anything made of heavier elements -- gold or silver or platinum, or (more prosaically) the zinc plating on a galvanized steel pipe -- ponder for a moment that it was formed in a catastrophically huge collision between two neutron stars, an event that released more energy in a few seconds than the Sun will produce over its entire lifetime.  Sometimes the most ordinary things have a truly extraordinary origin -- something that never fails to fascinate me.

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In the midst of a pandemic, it's easy to fall into one of two errors -- to lose focus on the other problems we're facing, and to decide it's all hopeless and give up.  Both are dangerous mistakes.  We have a great many issues to deal with besides stemming the spread and impact of COVID-19, but humanity will weather this and the other hurdles we have ahead.  This is no time for pessimism, much less nihilism.

That's one of the main gists in Yuval Noah Harari's recent book 21 Lessons for the 21st Century.  He takes a good hard look at some of our biggest concerns -- terrorism, climate change, privacy, homelessness/poverty, even the development of artificial intelligence and how that might impact our lives -- and while he's not such a Pollyanna that he proposes instant solutions for any of them, he looks at how each might be managed, both in terms of combatting the problem itself and changing our own posture toward it.

It's a fascinating book, and worth reading to brace us up against the naysayers who would have you believe it's all hopeless.  While I don't think anyone would call Harari's book a panacea, at least it's the start of a discussion we should be having at all levels, not only in our personal lives, but in the highest offices of government.